![]() Spending time with Ann on Valentine's Day will give Joker Ann's Chocolate, an item that restores all of an ally's SP, and Joker can go on a date with her on White Day. ![]() In a New Game Plus, this item will give players a bigger same-Arcana bonus when spending time with Ann. Players who reach the romance ending of Ann's story can invite her to spend Christmas Eve together, and her present is Earmuffs. Non-friends can also hang out with Ann at the post-festival party on 10/26 and get Ann Cream Puffs, a consumable that restores 100 SP for one ally. Ann will give Joker Menehune Dolls, an accessory that boosts max SP by 20 percent. If players haven't chosen the friendship path of rank 9 with Ann, Joker can spend time with her during the Hawaii free time event. Her favorite gifts are the Heart Ring, Uji Matcha Flan, Truffles, Castella, Bath of Roses, and Face Beautifier. Bringing Ann to the buffet in Shibuya will give players the Choco Fountain room decoration, and taking her to Harajuku will give players the Idol Poster. ![]() Joker can also invite Ann out if players don't have enough points to see the next ranking event yet, or if players have reached rank 10. Ann will also invite Joker for a daytime hangout on 8/6 at Meiji Shrine, but players might not see it if Ann or the Death confidant have already reached the friendship end, or if players haven't finished Futaba's Palace yet. Since this is an indoor spot, Ann will show up whether or not it's raining, but many of her events take place outdoors and won't be available if the weather is bad.Īnn will invite Joker to study together on the evenings of 5/9 and 7/11, and she'll ask him to see a movie together on 7/17. After that, she spends her days hanging out in the Shibuya Underground Mall in the southeast hallway on Tuesday, Wednesday, Friday, and Sunday. Her Persona is Carmen, the femme fatale who stars in the opera of the same name.įor her second rank event, players will find Ann in Joker's classroom after school. Its reverse represents difficulties in relationships, and so Ann represents the card both by being a model and by having a troubled friendship with Shiho. The Lovers Arcana in the Tarot deck represents love and romance, but also beauty and optimism.
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![]() Precipitaion colours - From Chemistry For Wa Stage 2 Units 2a and 2b by Chris Lewis and Peter Lewis Further reading (2004), "Preparation of 1-Butyl-3-methyl imidazolium-based Room Temperature Ionic Liquids", Org. ^ Dupont, J., Consorti, C., Suarez, P., de Souza, R.Journal of Inorganic and Nuclear Chemistry 32 (7): 2443. "On the preparation of metalloporphyrins". ![]() "A simplified synthesis for meso-tetraphenylporphine". Critical Reviews in Solid State and Materials Sciences 32 (1): 1–50. "Formation, Dynamics, and Characterization of Nanostructures by Ion Beam Irradiation". ![]() This simplifies the above equations to the following: Ag + (aq) + Cl − (aq) → AgCl (s) Precipitate coloursĪnything not on this list will (generally) form a white precipitate. In this case, any spectator ions (those that do not contribute to the reaction) are left out of the formula completely. Ag + (aq) + NO 3 − (aq) + K + (aq) + Cl − (aq) → AgCl (s) + K + (aq) + NO 3 − (aq)Ī final way to represent a precipitate reaction is known as a net ionic reaction. This reaction can be written emphasizing the dissociated ions in a combined solution. The silver chloride (AgCl) has formed a solid, which is observed as a precipitate. Representation using chemical equationsĪn example of a precipitation reaction: Aqueous silver nitrate (AgNO 3) is added to a solution containing potassium chloride (KCl), the precipitation of a white solid, silver chloride is observed. In metallurgy, precipitation from a solid solution is also a useful way to strengthen alloys this process is known as solid solution strengthening. Precipitation is also useful in purifying products: crude bmim-Cl is taken up in acetonitrile, and dropped into ethyl acetate, where it precipitates. An example would be the synthesis of chromic tetraphenylporphyrin chloride: water is added to the DMF reaction solution, and the product precipitates. Thereafter, the precipitate may easily be separated by filtration, decanting, or centrifugation). Precipitation may also occur when an antisolvent (a solvent in which the product is insoluble) is added, drastically reducing the solubility of the desired product. By cooling the reaction mixture to room temperature, crystals of the porphyrin precipitate, and are collected by filtration: An example of this would be the synthesis of porphyrins in refluxing propionic acid. Thus, it precipitates as it is formed, preferably forming pure crystals. Ideally, the product of the reaction is insoluble in the reaction solvent. ![]() Precipitation is also useful to isolate the products of a reaction during workup. Precipitation reactions can be used for making pigments, removing salts from water in water treatment, and in classical qualitative inorganic analysis. If this energy is not available, and no suitable nucleation surface is available, supersaturation occurs.Ĭrystals of meso-tetratolylporphyrin from refluxing propanoic acid precipitate on cooling The creation of a hypothetical solid particle includes the formation of an interface, which requires some energy based on the relative surface energy of the solid and the solution. Īn important stage of the precipitation process is the onset of nucleation. Precipitation in solids is routinely used to synthesize nanoclusters. rapid quenching or ion implantation, and the temperature is high enough that diffusion can lead to segregation into precipitates. In solids, precipitation occurs if the concentration of one solid is above the solubility limit in the host solid, due to e.g. With soluble substances, precipitation is accelerated once the solution becomes supersaturated. During chemical reactions, precipitation may also occur particularly if an insoluble substance is introduced into a solution and the density happens to be greater (otherwise the precipitate would float or form a suspension). Natural methods of precipitate include settling or sedimentation, where a solid forms over a period of time due to ambient forces like gravity or centrifugation. Powders derived from precipitation have also historically been known as flowers. The liquid remaining above the solid is in either case called the supernate or supernatant. When the reaction occurs in a liquid, the solid formed is called the Precipitate, or when compacted by a centrifuge, a pellet. Precipitation is the formation of a solid in a solution or inside another solid during a chemical reaction or by diffusion in a solid. ![]() This article references metric terminology introduced in our Monitoring 101 series, which provides a framework for metric collection and alerting.Ĭount of executed statements (sent by client only)Ĭount of executed statements (sent by client or executed within stored programs) And the version of MariaDB (10.0.17) available on RDS at the time of this writing is not fully compatible with the MySQL Workbench tool or the sys schema, both of which are detailed in Part 2 of this series. For instance, Aurora has auto-scaling storage and therefore does not expose a metric tracking free storage space. Most of the performance metrics outlined here also apply to Aurora and MariaDB on RDS, but there are some key differences between the database engines. Part 2 of this series explains how to collect both types of metrics. ![]() MySQL metrics, on the other hand, must be accessed from the database instance itself. RDS metrics (as opposed to MySQL metrics) are available through Amazon CloudWatch, and are available regardless of which database engine you use. In this article we’ll highlight key metrics in each of the above areas that together give you a detailed view of your database’s performance. ![]() Users of MySQL on RDS have access to hundreds of metrics, but it’s not always easy to tell what you should focus on. To keep your applications running smoothly, it is important to understand and track performance metrics in the following areas: This article focuses on the original RDS database engine: MySQL. RDS users can choose from several relational database engines, including MySQL, Oracle, SQL Server, Postgres, MariaDB, and Amazon Aurora, a new MySQL-compatible database built for RDS. What is RDS?Īmazon Relational Database Service (RDS) is a hosted database service in the AWS cloud. Part 2 is about collecting metrics from both RDS and MySQL, and Part 3 details how to monitor MySQL on RDS with Datadog. This post is part 1 of a 3-part series about monitoring MySQL on Amazon RDS. ![]() On most Linux-distros, after re-mount of micro-SD-card, run: ```touch /media/$user/boot/ssh```. Create or copy a file called ssh in /boot. This will currently only work with 64-bit capable Raspberry Pi and Pi OS that is 64-bit.įor security reasons, as of the November 2016 release, Raspbian OS has the SSH server disabled by default. ![]() odinb/bash-plexamp-installer/blob/main/README.md # PlexAmp-installer for Raspberry Pi with ARM64 HW.įor more information and hardware used, see here: Ĭurrently installs/upgrades to: Plexamp Headless v4.2.2īurn the OS-image to the Micro-SD card using Raspberry pi imager, etcher (or app of your choice). If anyone has any suggestions for a solution or has any context for what may be causing it would be greatly appreciated. I have tried it with both my Raspberry Pi 3B and Pi 3B+ using Debian Bullseye Lite 64 Bit. I have attached the Audio+ V2 up to my AV Receiver and a set of powered bookshelf speakers I have and changing between them appears to have no affect. The problem exists both with the test sound when first installing the driver for raspberry pi in addition to how I am playing the audio from my plex library, linked below. The problem I am facing now is that the audio works but sounds like a box is put in front of my speakers with how muffled they sound. If anyone has any insight into how that ipv6 address got into /etc/nf I’d be interested to hear.I purchased a coupled of Audio+ V2 shields with the intention of getting them set up to as an alternative to Sonos for streaming audio from my plex media server in my house. I confirmed /etc/nf looks the same on another of my rpis with Tailscale, though not on my Mac which just lists my router IP as the nameserver.Īnd now Plex works as expected! Locally and remotely, both with the Tailscale IP and the Tailscale hostname. Which I didn’t expect, but my guess is this is how MagicDNS works (I do have that enabled), so I guess makes sense. Now /etc/nf seems to have been generated by Tailscale! # Generated by resolvconf I modified it to Google’s DNS servers: static domain_name_servers=8.8.8.8 8.8.4.4Īnd rebooted. I found the relevant setting in /etc/nf was blank: static domain_name_servers= etc/nf is auto-generated (from settings in /etc/nf apparently), so I rebooted (twice) to make sure that setting was current and persistent, and it was. I don’t know why, nor where it came from, nor what that address maps too, as I have ipv6 disabled on the Pi and my router doesn’t have ipv6 enabled. I checked the Pi’s /etc/nf and found it had an ipv6 address for nameserver. So, looks like DNS problems, maybe ipv6 related (those 6s looks suspicious to me). Watching the Plex logs I noticed errors like: 10:54:15.536 WARN - HTTP error requesting GET (6, Couldn't resolve host name) (Could not resolve host: )Īnd 10:35:10.666 ERROR - HTTP -6 downloading url ġ0:35:10.666 INFO - AutoUpdate: error getting data from Writing it up here in case it helps anyone. Should this just work, or is there something else to configure? Have I missed something? Similarly if I use my phone’s hotspot and try from outside my local network - “Something went wrong”. shows a Plex page with the msg “Something went wrong”, and my library, settings etc are not accessible. But that does not work if I use the Tailscale IP, nor the Tailscale hostname. On the same local network as the Pi, if I visit 192.168.1.22:32400 (the Pis local/internal IP) I can browse the Plex UI and see my library etc. However I run Plex on one of the Pis, and I can’t access the web UI over Tailscale. This works whether I am on the same local wifi network, or if I use my phone’s hotspot (ie through my mobile provider, not local network). ![]() I can also ssh etc, everything seems fine - using either the Tailscale hostname or the Tailscale IP. I have it installed on my Mac and a couple of Raspberry Pis. Windows Media player should now be reinstalled. How to rename music files automatically in Windows Media Player To enable this option under Windows Media Player, follow this procedure: Click on the Tools menu > Options > Library. Scroll down and expand Media Features, select the Windows Media Player check box, and click OK. 27/09/22 16:27 In this short guide, we will show you how to automatically rename MP3 in Windows Media Player using rip music settings. Windows Media Player should be uninstalled. Most portable music players, including the iPod, also rely on tags. If you cannot spot Windows Media Player in the list, check out if there’s any file by the name WMPlayer.exe located under the Windows Media Player folder in the Program Files directory. When deciding how to sort, display, and categorize your music, Windows Media Player reads those tags not the songs’ filenames. Scroll down and expand Media Features, clear the Windows Media Player check box, and click OK. What's a song tag It’s a small form that contains the song’s title, artist, album, and other related information. If you want to reinstall Windows Media Player, try the following:Ĭlick the Start button, type features, and select Turn Windows features on or off. For Windows 7 N or KN editions, get the Media Feature Pack. Included in Windows 7 Starter, Home Premium, Professional, Ultimate, and Enterprise editions. Windows Media Player isn't available for Windows RT 8.1. For Windows Media Player 12 for Windows 8.1 N and KN editions, get the Media Feature Pack. Go to the DVD playback for Windows page to find out how to add DVD playback to Windows 8.1. ![]() C:\documents and settings\my name\my documents\ This thread is locked. You can identify the album, artist, genre, tracks, title, contributing artist, and composer. where is library located for windows media player - Microsoft Community LA Larry898 Created on Januwhere is library located for windows media player can anyone tell me the path for the windows media player library windows xp explorer. Included in Windows 8.1 and Windows 8.1 Pro, but doesn't include DVD playback. Fill in the tag information the way you want it to appear. Go to the DVD playback for Windows page to find out how to add DVD playback to Windows 10. To do that, select the Start button, then select Settings > Apps > Apps ![]() Not much went wrong with our Carnival, but its scheduled maintenance costs did total a relatively high $1091, and Kia doesn't offer complimentary maintenance like some of its rivals do. Deputy video editor Carlos Lago also liked the "jazzed-up" cabin, with its patterned metal trim, good-looking display screens, and easy-to-use knobs for the audio system and HVAC controls. It doesn't entirely pull off the trick, as the Carnival still has the unmistakable sliding doors and large windows of a van, but we heard from friends that the look of this Kia could convince them to consider a minivan for the first time. Kia has attempted to make the minivan-with its cleverly placed C-pillar trim and a more prominent nose-look like an SUV. That sentiment was shared among the staff, as the Carnival's design impressed inside and out. ![]() "Would I get the Carnival instead of the Sienna that gets 50 percent better fuel economy?" mused editor-in-chief Tony Quiroga. It averaged 29 mpg, offered all-wheel drive, and was only a few ticks slower than the V-6-powered Carnival, which got to 60 mph in 7.4 seconds at the end of its test. That's perfectly fine, but our recent long-term test of a Toyota Sienna minivan, which comes only as a hybrid, has shown us that there's a better way. The Carnival matched its EPA combined rating during its stay with us, averaging 22 mpg. Our van's dual-screen rear entertainment system is also now optional rather than standard on the SX Prestige model. They no longer come standard on the top trim (an eight-seat layout is the default setup) and are now a no-cost option. Indeed, Kia appears to have listened, as it has made the VIP seats less available on the 2023 Carnival. The fact that you can't remove them also proved annoying when hauling large items. Others found their operation clunky, and they robbed the third row of space for passengers. For some, they were a nice refuge, perfect for napping on road trips. We had mixed feelings about the second-row VIP Lounge seats with their myriad power adjustments and leg rests. And, of course, we stuffed the Carnival's seven-seat interior full of our own precious cargo, frequently making use of its spacious cabin and creature comforts. We knew we'd be doing some hauling with this van-and we did, strapping stuff to the roof on occasion and even towing a small U-Haul trailer that was well under the 3500-pound towing capacity. Finished in $495 Astra Blue paint, our van stickered for $49,000 and included a tow hitch and roof-rack crossbars for maximum utility. Wanting to test out all the gadgets and gizmos the Carnival has to offer, we chose a loaded SX Prestige model. Slightly more than a year later, we can report that the Kia Carnival not only lives up to expectations for the sliding-door species but also continues to cement Kia's newfound reputation for building desirable, high-quality, and functional vehicles-no matter the form they take. As minivan connoisseurs ourselves, we promptly ordered one up for a 40,000-mile test. It even christened it with a new name, Carnival, to replace the old Sedona moniker. Kia has a great one of those, too, in the 10Best-winning Telluride, but still chose to reup its van for a fourth generation for 2022. Many automakers killed off their people-haulers years ago in favor of three-row SUVs. Kia's overall excellence is becoming so pervasive that even its products in dwindling segments-like minivans-are now among the class leaders. ![]() You also can’t guarantee that the resulting puppy will even look like a miniature Boxer. It also changes their personality and other factors.Ī miniature Boxer typically does not act exactly like a Boxer because of this. Of course, when you mix the Boxer breed with a smaller dog, you don’t just change their appearance. These breed combinations may all be called “miniature Boxers”. However, this designer breed is usually bred with some smaller breed that looks similar to the Boxer is used, like the Boston Terrier, Rat Terrier, Bull Terrier, or Fox Terrier. Usually, this is done by breeding them with a smaller dog. These dogs can be made smaller in a variety of ways. However, some dogs are often marketed as “miniature” to pull in potential buyers.
If you would like to see a donation link for the application here, please include one in the AppStream data. You can specify the URL to a nicer one by shipping an AppStream metainfo file. The screenshot for Postman has been automatically taken during a fully automated test. There is an online tool that makes it easy to make one. Improve this entry by shipping an AppStream metainfo file inside the AppImage in the usr/share/metainfo directory. Tools like appimagetool and linuxdeployqt can do this for you easily. zsync file so that it can be updated using AppImageUpdate. Were using Simple Books API whose documentation can be found in the resources section of this lesson below. Please consider to add update information to the Postman AppImage and ship a. Download Postman App Open Postman on the web Postman Desktop Agent (scroll down) Lesson 4 - Your first request with Postman - Main ideas To use an API you need to read the API documentation. Pro Tips for further enhancing the Postman AppImage Great! Here are some ideas on how to make it even better. Thanks for distributing Postman in the AppImage format for all common Linux distributions. Or, if you prefer a browser experience, you can try the web version of Postman. If you would like to have the executable bit set automatically, and would like to see Postman and other AppImages integrated into the system (menus, icons, file type associations, etc.), then you may want to check the optional appimaged daemon. Download the app to get started using the Postman API Platform today. If you would like to update to a new version, simply download the new Postman AppImage. This is entirely optional and currently needs to be configured by the user. If you want to restrict what Postman can do on your system, you can run the AppImage in a sandbox like Firejail. Then double-click the AppImage in the file manager to open it. Use at your own risk!ĭownload the Postman AppImage and make it executable using your file manager or by entering the following commands in a terminal: ![]() Follow these instructions only if you trust the developer of the software. ![]() This is a Linux security feature.īehold! AppImages are usually not verified by others. However, they need to be marked as executable before they can be run. Unlike other applications, AppImages do not need to be installed before they can be used. Running Postman on Linux without installation Most AppImages run on recent versions of Arch Linux, CentOS, Debian, Fedora, openSUSE, Red Hat, Ubuntu, and other common desktop distributions. No system libraries or system preferences are altered. Download an application, make it executable, and run! No need to install. Awesome!ĪppImages are single-file applications that run on most Linux distributions. Postman is available as an AppImage which means "one app = one file", which you can download and run on your Linux system while you don't need a package manager and nothing gets changed in your system. lefties) that ranked fifth among qualified hitters. Let’s start with the basics, offense first: Ohtani, who turned 27 in July, batted. With a leadoff homer and two walks on Sunday, Ohtani closed the book on his singular campaign, allowing us to size up his exquisite stats in their final form. Ohtani’s exploits as a full-time hitter and roughly full-time pitcher prompted comparisons to pre-integration greats such as Babe Ruth, Bullet Rogan, and Martín Dihigo, but no major leaguer-let alone a major leaguer facing something close to current competition-has ever combined power hitting, power pitching, and speed at the level and volume that Ohtani did in 2021. All of which means that even though MLB’s postseason is starting on Tuesday, Shohei Ohtani’s season is already over.Įarly exit notwithstanding, 2021 was and always will be the year of two-way Ohtani. Despite dousing their run-differential-defying division rival’s hopes of an elusive playoff appearance, the Angels finished 77-85, giving them their sixth consecutive losing record and fourth consecutive fourth-place finish in the AL West. The Angels were eliminated from postseason contention on September 21, but they posed successfully as spoilers over the regular season’s closing weekend, downing the Mariners 7-3 in Game 162 to take two of three from the M’s. Just not, you know, playoff implications for them. ![]() ![]() Amid MLB’s anticlimactic tiebreaker tease on Sunday, the Los Angeles Angels played a game with playoff implications. ![]() His heart is rushing because he knows the risk: he had already had much pain in the past because of other girls, so he hopes she understands the importance of his feelings.Īs I reach my house, I say make a rest small,ĭay one, day two-wo, I no fit foc-o-us (I no fit focus) That’s why the rapper opens up his heart and confesses his love. But it doesn’t work: the morning after he wakes up, she’s still in his mind, and there stays for days. Then Rema returns home and sleeps, trying to forget about this girl. ![]() ‘Cause her friends go dey gum her like chewing gum, woah I know say she sabi pass that one, one (Mhmm) Naim, I dey find situation, I go use take tell am helloįinally, I find way to talk to the girl but she no wan follow I see this fine girl, for my party she wear yellowĮvery other girl they dey do too much but this girl mellow He intends to show that his feelings are real and he doesn’t want to play with her. She felt insecure, so Rema tells her to calm down. The first verse explains how Rema approached this girl and how she refused to follow him. No tell me no, no, no, no, woah, woah, woah, woahīaby, come gimme your lo lo lo lo woah woah woah woah If I tell you say, “I love you”, you no dey form yanga oh, oh yanga oh Girl, you sweet like Fanta, ooh, Fanta, ooh Girl, this your body e put in my heart for lockdown, for lockdown, oh lockdown He wants to tell her how sweet she is and how she stole his heart. In the chorus, Rema says, “baby, calm down,” assuming she’s as shy as him. The song explains how the rapper would talk to this girl, trying to explain his feelings. In the lyrics, Rema tells us how she met a girl dressed in yellow at a party, and his heart started rushing. “Baby Calm Down”: the song lyrics and their meaningĬalm Down is a song about the difficulty of confessing love to someone. |
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